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Abstract Biodiesel is an alternative fuel consisting of the alkyl monoesters of fatty acids from vegetable oils or animal fats. Previous research has shown that biodiesel-fueled engines produce less carbon monoxide, unburned hydrocarbons, and particulate emissions compared to diesel fuel. One drawback of biodiesel is that it is more prone to oxidation than petroleum-based diesel fuel. In its advanced stages, this oxidation can cause the fuel to become acidic and to form insoluble gums and sediments that can plug fuel filters. The objective of this study was to evaluate the impact of oxidized biodiesel on engine performance and emissions. A John Deere 4276T turbocharged DI diesel engine was fueled with oxidized and unoxidized biodiesel and the performance and emissions were compared with No. 2 diesel fuel. The neat biodiesels, 20% blends, and the base fuel (No. 2 diesel) were tested at two different loads (100 and 20%) and three injection timings (3° advanced, standard; 3° retarded). The tests were performed at steady-state conditions at a single engine speed of 1400 rpm. The engine performance of the neat biodiesels and their blends was similar to that of No. 2 diesel fuel with the same thermal efficiency, but higher fuel consumption. Compared with unoxidized biodiesel, oxidized neat biodiesel produced 15 and 16% lower exhaust carbon monoxide and hydrocarbons, respectively. No statistically significant difference was found between the oxides of nitrogen and smoke emissions from oxidized and unoxidized biodiesel.

Dennis Y.C. Leung Department of Mechanical Engineering, The University of Hong Kong, Hong Kong email: ycleung@hku.hk Abstract All fuel usage produces air pollutants, causing local and trans-boundary air pollution and acid rain problems. Biodiesel is a clean renewable fuel with properties similar to diesel but produced from renewable resources such as vegetable oils and animal fats. Although this fuel has been developed some two to three decades ago, it is not commonly used, mainly due to the higher production cost involved. Due to the increasing concern on environmental protection, a lot of researches on the usage of this fuel are conducted in recent years. To study the characteristics of this fuel, a special biodiesel fuel is produced using waste cooking oil and animal fat from restaurants as feedstock. Reusing of these wastes has both the benefit of producing a cleaner fuel and waste cycling. Tests of the fuel with different proportions of diesel have been conducted on various diesel engines and the results obtained are encouraging. The environmental benefits and suitability of this fuel to Hong Kong to reduce air pollution problems are discussed based on the assessment results.

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