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지식나눔

지식나눔

peroxyphenylacetic acid 합성방법좀 알려주세요 ^^

2007-11-02 org.kosen.entty.User@1dfef7b8 박병권(pbk14)
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peroxyphenylacetic acid 합성방법좀 알려주세요 구조 첨부합니다
  • peroxyphenylacetic acid
  • PPAA
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    2007-11-03
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    > peroxyphenylacetic acid 합성방법좀 알려주세요 >구조 첨부합니다 함께 첨부한 파일에서 14번 문헌의 Abstrct이 아래에 있습니다. 연구에 작은 도움이 되시길 빕니다. The formation of peracids by the perhydrolysis with alkaline hydrogen peroxide Y. Ogata and Y. Sawaki Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya, Japan Received 3 October 1966; accepted 13 December 1966. Available online 12 March 2001. Abstract A high yield (ca. 90%) of perbenzoic acid has been obtained in the alkaline perhydrolysis of benzoyl peroxide by suppressing the decomposition of the peracid with excess alkali and a little magnesium sulfate in aqueous organic solvents. This perhydrolysis method has been applied to other substrates, e.g. benzoyl chloride, phthalic anhydride and acetyl chloride giving 85–90% yields. The perhydrolysis of benzoyl chloride has been shown to proceed, partially at least, through the intermediary formation of benzoyl peroxide. Tetrahedron Volume 23, Issue 8, 1967, Pages 3327-3332
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    > peroxyphenylacetic acid 합성방법좀 알려주세요 >구조 첨부합니다 함께 첨부한 파일에서 14번 문헌의 Abstrct이 아래에 있습니다. 연구에 작은 도움이 되시길 빕니다. The formation of peracids by the perhydrolysis with alkaline hydrogen peroxide Y. Ogata and Y. Sawaki Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya, Japan Received 3 October 1966; accepted 13 December 1966. Available online 12 March 2001. Abstract A high yield (ca. 90%) of perbenzoic acid has been obtained in the alkaline perhydrolysis of benzoyl peroxide by suppressing the decomposition of the peracid with excess alkali and a little magnesium sulfate in aqueous organic solvents. This perhydrolysis method has been applied to other substrates, e.g. benzoyl chloride, phthalic anhydride and acetyl chloride giving 85–90% yields. The perhydrolysis of benzoyl chloride has been shown to proceed, partially at least, through the intermediary formation of benzoyl peroxide. Tetrahedron Volume 23, Issue 8, 1967, Pages 3327-3332
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