지식나눔

유기반응에서 산화제가 어떠한것들이 있나요??

안녕하세요 제가 유기반응을 하려고하는데 O2조건을 여건상 할 수 없어서 산화제 oxiadant로 대체하려고 합니다. 여기에 대한 지식이 별로 없어서 그런데 산화제로 쓰이는 시약이 무엇무엇이 있는지 궁금합니다. 감사합니다.
 
  • 유기화학
  • 합성
  • 산화제
지식의 출발은 질문, 모든 지식의 완성은 답변! 
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답변 2
  • 답변

    이배훈님의 답변

    등록된 댓글이 없습니다.
  • 답변

    김강형님의 답변

    첨부파일

    http://www.sigmaaldrich.com/chemistry/chemistry-products.html?TablePage=16277367
    http://www.organic-chemistry.org/chemicals/oxidations/dp 에 소개되어 있습니다.

    Chromates - (28종)
    Hypervalent Iodine - (36종)
    Hypochlorites - (6)
    Osmium - (9)
    Perchlorates - (59)
    Peroxides - (58)
    Peroxy Acids and Salts - (7)
    Sulfur-Based - (24)
    Others - (75)

    알파벳 순서로는
    ABNO

    Acetone

    Ammonium cerium (IV) nitrate

    Ammonium peroxydisulfate

    2-Azaadamantane N-oxyl

    9-Azabicyclo[3.3.1]nonane N-oxyl

    AZADO

    9-Azanoradamantane N-oxyl

    1,4-Benzoquinone

    Benzoyl peroxide

    Bleach

    N-Bromosaccharin

    N-Bromosuccinimide

    (E)-But-2-enenitrile

    N-Fluoro-2,4,6-trimethylpyridinium triflate

    N-tert-Butylbenzenesulfinimidoyl chloride

    tert-Butyl hydroperoxide

    tert-Butyl hypochlorite

    tert-Butyl nitrite

    CAN

    Cerium ammonium nitrate

    Chloramine-T

    Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

    3-Chloroperoxybenzoic acid

    Chromium compounds

    Chromium trioxide

    Collins Reagent

    Corey-Suggs Reagent

    CMHP

    Copper compounds

    Crotononitrile

    Cumene hydroperoxide

    DBDMH

    DDQ

    DEAD

    Dess-Martin periodinane

    DIAD

    1,3-Dibromo-5,5-dimethylhydantoin

    2,3-Dichloro-5,6-dicyanobenzoquinone

    Diethyl azodicarboxylate

    DIH

    1,3-Diiodo-5,5-dimethylhydantoin

    Diisopropyl azodicarboxylate

    Dimethyl sulfoxide

    Di-tert-butyl peroxide

    DPQ

    DTBP

    (E)-But-2-enenitrile

    Ferric chloride

    Ferric nitrate

    N-Fluoro-2,4,6-trimethylpyridinium triflate

    Formic acid

    Hydrogen peroxide

    Hydrogen peroxide urea adduct

    Hydroxy(tosyloxy)iodobenzene

    Hypervalent bromine compounds

    Hypervalent iodine compounds

    HTIB

    IBX

    Iodine

    Iodobenzene dichloride

    Iodosobenzene bis(trifluoroacetate)

    Iodosobenzene diacetate

    N-Iodosuccinimide

    Iodosylbenzene

    2-Iodoxybenzoicacid

    Iron(III), (V) and (IV)

    Jones Reagent

    Koser's Reagent

    Magnesium monoperoxyphthalate hexahydrate

    Manganese compounds

    Manganese(IV) oxide

    MCPBA

    meta-Chloroperbenzoic acid

    N-Methylmorpholine-N-oxide

    Methyltrioxorhenium

    MMPP • 6 H2O

    Molybdenum compounds

    MTO

    N-Bromosaccharin

    N-Bromosuccinimide

    N-Chloro tosylamide sodium salt

    N-Chlorosuccinimide

    N-Iodosuccinimide

    N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide

    Nitric Acid

    Nitrosobenzene

    N-Methylmorpholine-N-oxide

    NMO

    Nor-AZADO

    N-tert-Butylbenzenesulfinimidoyl chloride

    Osmium tetroxide

    Oxalyl chloride

    Oxone

    Oxygen

    Ozone

    PCC

    PDC

    Peracetic acid

    Periodic acid

    Peroxides

    Peroxy acids

    Phenyliodonium diacetate

    PIFA

    Pivaldehyde

    Potassium ferricyanide

    Potassium permanganate

    Potassium peroxydisulfate

    Potassium peroxomonosulfate

    2-Propanone

    Pyridine N-oxide

    Pyridinium hydrobromide perbromide

    Pyridinium chlorochromate

    Pyridinium dichromate

    Pyridinium tribromide

    Ruthenium (III - VII) compounds

    Sarett Reagent

    Selectfluor

    Selenium dioxide

    Sodium bromate

    Sodium chlorite

    Sodium dichloroiodate

    Sodium hypochlorite

    Sodium nitrite

    Sodium perborate

    Sodium percarbonate

    Sodium periodate

    Sulfur

    Styrene

    TBCA

    TBHP

    TBN

    TCBDA

    TCCA

    TEMPO

    N-tert-Butylbenzenesulfinimidoyl chloride

    tert-butyl hydroperoxide

    tert-Butyl hypochlorite

    tert-Butyl nitrite

    Tetrabutylammonium peroxydisulfate

    N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide

    2,2,6,6-Tetramethylpiperidinyloxy

    Tetrapropylammonium Perruthenate

    3,3',5,5'-Tetra-tert-butyldiphenoquinone

    TPAP

    Triacetoxyperiodinane

    Tribromoisocyanuric acid

    Trichloroisocyanuric acid

    1,1,1-Trifluoroacetone

    Trifluoroacetic peracid

    Trimethylacetaldehyde

    UHP

    Urea hydrogen peroxide adduct

    Vanadium compounds

    http://www.sigmaaldrich.com/chemistry/chemistry-products.html?TablePage=16277367
    http://www.organic-chemistry.org/chemicals/oxidations/dp 에 소개되어 있습니다.

    Chromates - (28종)
    Hypervalent Iodine - (36종)
    Hypochlorites - (6)
    Osmium - (9)
    Perchlorates - (59)
    Peroxides - (58)
    Peroxy Acids and Salts - (7)
    Sulfur-Based - (24)
    Others - (75)

    알파벳 순서로는
    ABNO

    Acetone

    Ammonium cerium (IV) nitrate

    Ammonium peroxydisulfate

    2-Azaadamantane N-oxyl

    9-Azabicyclo[3.3.1]nonane N-oxyl

    AZADO

    9-Azanoradamantane N-oxyl

    1,4-Benzoquinone

    Benzoyl peroxide

    Bleach

    N-Bromosaccharin

    N-Bromosuccinimide

    (E)-But-2-enenitrile

    N-Fluoro-2,4,6-trimethylpyridinium triflate

    N-tert-Butylbenzenesulfinimidoyl chloride

    tert-Butyl hydroperoxide

    tert-Butyl hypochlorite

    tert-Butyl nitrite

    CAN

    Cerium ammonium nitrate

    Chloramine-T

    Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

    3-Chloroperoxybenzoic acid

    Chromium compounds

    Chromium trioxide

    Collins Reagent

    Corey-Suggs Reagent

    CMHP

    Copper compounds

    Crotononitrile

    Cumene hydroperoxide

    DBDMH

    DDQ

    DEAD

    Dess-Martin periodinane

    DIAD

    1,3-Dibromo-5,5-dimethylhydantoin

    2,3-Dichloro-5,6-dicyanobenzoquinone

    Diethyl azodicarboxylate

    DIH

    1,3-Diiodo-5,5-dimethylhydantoin

    Diisopropyl azodicarboxylate

    Dimethyl sulfoxide

    Di-tert-butyl peroxide

    DPQ

    DTBP

    (E)-But-2-enenitrile

    Ferric chloride

    Ferric nitrate

    N-Fluoro-2,4,6-trimethylpyridinium triflate

    Formic acid

    Hydrogen peroxide

    Hydrogen peroxide urea adduct

    Hydroxy(tosyloxy)iodobenzene

    Hypervalent bromine compounds

    Hypervalent iodine compounds

    HTIB

    IBX

    Iodine

    Iodobenzene dichloride

    Iodosobenzene bis(trifluoroacetate)

    Iodosobenzene diacetate

    N-Iodosuccinimide

    Iodosylbenzene

    2-Iodoxybenzoicacid

    Iron(III), (V) and (IV)

    Jones Reagent

    Koser's Reagent

    Magnesium monoperoxyphthalate hexahydrate

    Manganese compounds

    Manganese(IV) oxide

    MCPBA

    meta-Chloroperbenzoic acid

    N-Methylmorpholine-N-oxide

    Methyltrioxorhenium

    MMPP • 6 H2O

    Molybdenum compounds

    MTO

    N-Bromosaccharin

    N-Bromosuccinimide

    N-Chloro tosylamide sodium salt

    N-Chlorosuccinimide

    N-Iodosuccinimide

    N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide

    Nitric Acid

    Nitrosobenzene

    N-Methylmorpholine-N-oxide

    NMO

    Nor-AZADO

    N-tert-Butylbenzenesulfinimidoyl chloride

    Osmium tetroxide

    Oxalyl chloride

    Oxone

    Oxygen

    Ozone

    PCC

    PDC

    Peracetic acid

    Periodic acid

    Peroxides

    Peroxy acids

    Phenyliodonium diacetate

    PIFA

    Pivaldehyde

    Potassium ferricyanide

    Potassium permanganate

    Potassium peroxydisulfate

    Potassium peroxomonosulfate

    2-Propanone

    Pyridine N-oxide

    Pyridinium hydrobromide perbromide

    Pyridinium chlorochromate

    Pyridinium dichromate

    Pyridinium tribromide

    Ruthenium (III - VII) compounds

    Sarett Reagent

    Selectfluor

    Selenium dioxide

    Sodium bromate

    Sodium chlorite

    Sodium dichloroiodate

    Sodium hypochlorite

    Sodium nitrite

    Sodium perborate

    Sodium percarbonate

    Sodium periodate

    Sulfur

    Styrene

    TBCA

    TBHP

    TBN

    TCBDA

    TCCA

    TEMPO

    N-tert-Butylbenzenesulfinimidoyl chloride

    tert-butyl hydroperoxide

    tert-Butyl hypochlorite

    tert-Butyl nitrite

    Tetrabutylammonium peroxydisulfate

    N,N,N',N'-Tetrachlorobenzene-1,3-disulfonamide

    2,2,6,6-Tetramethylpiperidinyloxy

    Tetrapropylammonium Perruthenate

    3,3',5,5'-Tetra-tert-butyldiphenoquinone

    TPAP

    Triacetoxyperiodinane

    Tribromoisocyanuric acid

    Trichloroisocyanuric acid

    1,1,1-Trifluoroacetone

    Trifluoroacetic peracid

    Trimethylacetaldehyde

    UHP

    Urea hydrogen peroxide adduct

    Vanadium compounds

    등록된 댓글이 없습니다.