네트워크

화공

고분자박막 연구실

Research Overview
 
  Research by our laboratory mainly focuses on the fundamental and applied aspects of thin films involving macromolecules
and nano-objects. The current emphasis of our research program is placed on the fabrication and characterization of block
copolymer thin films, ultra thin functional multilayer films, nanoporous thin films, hybridization and their.
Our research group has already established synthetic schemes to prepare well-defined nanomaterials such as block
copolymers, quantum dots, organosilicates, and hollow metal oxide nano-objects with various functionalities. Furthermore, fundamental knowledge on the interfacial manipulation at the molecular level accumulated in this research group can be directly applied to realize integrated devices or hierarchical structures with unique functions.
 
 
 Patterning of functional nano-objects with block copolymer templates
 Polymer-based platforms (polymer / polymer, polymer / nano-object or nano-object / nano-object multilayers and their patterns)    based on the Layer-by-Layer (LbL) deposition method
 Organic / inorganic nanohybrids for energy / environmental applications
 Unconventional patterning of multilayer films for biological and optoelectronic applications
 Fabrication of nano / mesoporous organosilicate thin films with low dielectric (refractive) constant
 Enhancement in power conversion efficiency in photovoltaic devices by the modification of interfaces
 Large-scale synthesis of well-defined RGB quantum dots (QDs) with high quantum yield
 
 
Research Details
 
  Self-Assembly of Amphiphilic Macromolecules and Their Applications

Self-assembled block copolymers (BCP) are expected to serve as useful soft nanotemplates for a host of potential applications
by adjusting chemical and physical structures of BCPs at the molecular level. One representative example for the utilization of
block copolymer nanostructure is the fabrication of perpendicularly oriented nanostructure to realize nanodot or nanowire arrays.
To control the specific orientation of BCP microdomains, our research group has actively been engaged in developing several
surface engineering techniques based on the characterization and manipulation of surfaces and interfaces of BCP films. In
addition, the defect minimization in large area for practical applications is required to realize high performance devices such
as next generation tetabit memory devices and revolutionary fabrication methods for the defect minimization of self-assembled
domains is currently being developed in our laboratory.
 
 
 
 

Functional Thin Films Based on Layer-by-Layer Deposition

The Layer-by-Layer (LbL) deposition has received intensive attention in past decade due to its simple fabrication procedure
and yet broad potential applications such as functional ultra thin multilayer films, surface modification of substrates, and
hybridization of functional nanomaterials. Our group has the reputation in the development of a new class of LbL deposition
based on the spin self-assembly process, which is much simpler and faster than the conventional dip-based deposition method.
This fabrication method results in the highly ordered internal structure suitable for high performance devices such as
ultra thin capacitors and bio- and environmental sensors. In addition, our research group has recently extended
the LbL deposition involving various functional nano-objects such as nanoparticles, nanowires, and micelles,
to upgrade the functions embedded in thin films to the next dimension.

 
 
 
 

Nanoporous Materials for Optoelectronic Applications

Nanoporous organic and/or inorganic thin films provide a variety of potential applications such as intermetallic dielectric
materials, optical components, sensor elements, and substrates for biological applications. Nanoporous structure can generally
be created by the introduction of pore-generating materials (porogens) to thin films followed by the selective removal of such
porogens by post treatments such as solvent etching, UV-, thermal-, acid-, or salt-treatment. Our research group has reported
the world-best nanoporous thin films with balanced mechanical and low dielectric properties for next generation semiconductor
devices, based on judiciously designed organosilicates and norbornene copolymers. In addition, our laboratory has recently
worked out a strategy to prepare well-defined hollow inorganic nanospheres, which can be applied to areas such as solid-state
lighting and photocatalysts.

 

국가

대한민국

소속기관

서울대학교 (학교)

연락처

책임자

차국헌 khchar@plaza.snu.ac.kr

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