Adsorption, separation, and catalytic properties of densified metal-organic frameworks
2016-02-14
org.kosen.entty.User@1b98094a
오현철(dhguscjf)
행사&학회소개
1. Introduction
2. Properties and applications of densified MOFs
2.1. Hydrogen storage properties of densified MOF-5
2.2. Densification of water stable Zr-based MOFs
2.3. Adsorption and separation properties of densified HKUST-1
2.4. Densification of flexible MOFs (MIL-53) for CH4/CO2 separation
2.5. Densified MIL-101(Cr) for adsorption and separation
2.6. Densification of mechanically robust ZIF-8
3. Conclusions and future perspectives
2. Properties and applications of densified MOFs
2.1. Hydrogen storage properties of densified MOF-5
2.2. Densification of water stable Zr-based MOFs
2.3. Adsorption and separation properties of densified HKUST-1
2.4. Densification of flexible MOFs (MIL-53) for CH4/CO2 separation
2.5. Densified MIL-101(Cr) for adsorption and separation
2.6. Densification of mechanically robust ZIF-8
3. Conclusions and future perspectives
보고서작성신청
The use of MOF powders for industrial applications often results in pressure drop problems similar to the case with zeolites and limited robustness against water. To realize these materials for practical applications, densification of MOFs (by increasing pellet density) is routinely employed to form pellets, extrudates or beads to improve the overall density, volumetric adsorption, mechanical and thermal properties. However, the improvements come with some drawbacks such as reduction in overall porosity, surface area, and gravimetric adsorption capacity. Thus, optimizing the properties of densified MOF's by tuning the pellet density is very crucial for realizing these materials for industrial applications.In this review, the properties and applications of densified MOFs with different metal clusters and organic linkers are discussed.